Nitrogen and Pyridine Adsorption on Chromia-Coated Silica and Alumina Catalysts: Probing the Chromia Dispersity

H2S adsorption on chromium, chromia, and gold/chromia surfaces: Photoemission studies

Pyridine Adsorption on Molybdenum Oxide-Alumina Catalysts

The adsorption of pyridine on a complete monolayer molybdenum oxide-Al203 catalyst was studied. Both Lewis and Bronsted acid sites are present on a catalyst with a Mo valence of -4.1. The orientation of adsorbed pyridine was studied by means of its interaction with surface OD groups, which leads to the formation of only 2-deuteriopyridine. The fraction of molybdenum ions active for hydrogenatio...

Densification characteristics of chromia/alumina castables by particle size distribution

The quality of the refractories applied on integrated gasification combined cycle should be a key factor that affects both the reliability and the economics of gasifier operation. To enhance the workability of chromia/alumina castables, three types of ultrafine alumina powder were added to improve the workability. Densification behavior of such castables in the presence of ultrafine alumina was...

The thermal diffusivity and conductivity of transformation-toughened solid solutions of alumina and chromia

The thermal diffusivity of a series of solid solutions of alumina and chromia transformation toughened with a dispersed phase of unstabilized zirconia was measured by means of the laser-flash method from room temperature to 1400 ~ C. It was found, in general, that the thermal diffusivity could be decreased significantly by the combined effects of solid solution alloying, microcracking and by th...

Magnetism of Chromia from First-Principles Calculations